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In Welcome to Super Hero High, Lady Shiva appears in front of Super Hero High School, talking to Fire as Principal Waller introduces the school for a promotional video. In All About Super Hero High, she appears in the video as it is being played on Wonder Woman's phone. She later appears in a school hallway, watching Hawkgirl chase Cheetah, and in the school foyer talking to Cyborg.
In Fall Into Super Hero High, she makes a background appearance in Harley Quinn's video attending Bumblebee's presentation on shrink and stretch spandex. In Hero of the Month: Wonder Woman, Lady Shiva watches as Wonder Woman gets announced Hero of the Month by Principal Waller in the school cafeteria.
In the special Super Hero High, Lady Shiva talks to Black Orchid in front of the school and greets Supergirl in Mandarin as she first arrives at Super Hero High School. She and other students later greets Wonder Woman and her friends when they return to the school after defeating Giganta and participates in the battle against the Female Furies after their mind control to take over the school is broken. She battles Stompa, but is thrown into a wall where she is caught by one of Poison Ivy's plants. She also appears in the crowd of students cheering for Principal Waller, Vice Principal Grodd, Wonder Woman, Supergirl and Batgirl as they exit from the boom tubes room after sending the Furies to Belle Reve Penitentiary.
In Hero of the Month: Supergirl, she appears in a yearbook photo in Supergirl's Hero of the month VT. In Batgirl vs Supergirl, she exits the school cafeteria and jumps over Batgirl's cable tied as Supergirl drags her by it, as they race into the cafeteria over the last piece of superfood cake.
In Hero of the Month: Harley Quinn, she watches Harley Quinn's Hero of the Month announcement in the Super Hero High library from a laptop, alongside Cheetah, Catwoman, Katana, Hawkgirl and Supergirl. In Franken-Ivy, she makes a background appearance talking to Miss Martian in the school hallway and later confronts Ivy's overgrown plant monster when it rampages through metropolis with other students.
In Hero of the Month: Hawkgirl, Shiva appears as a guest at Bumblebee's surprise birthday party, shown in Hawkgirl's Hero of the Month VT. In The Cheetah Who Cried Wolf, Shiva appears standing by Cyborg in the hallway as the Save the Day alarm goes off for one of the false crimes staged by the Cheetah. She later appears in the student lounge with Hawkgirl and Starfire reading a book, and they ignore Cheetah's when she tells them that Solomon Grundy is attacking the Senior's Center, after she stages more false alarms.
In Roomies Return: Frost's Bite, she greets Frost as she enters the dormitory kitchen they share with Miss Martian and Star Sapphire in the morning. She later appears racing other students to the showers and later ponders with Star Sapphire why Frost is so grumpy before they guile Miss Martian into finding out.
In The Odd Couple, Shiva gets partnered with Harley Quinn for an advanced stake-out class project, staking out on a building rooftop observing the streets at night for Cheshire, and left exasperated by Harley's lack of seriousness towards the assignment. They eventually encounter Cheshire, who attacks them and they jump off the rooftop. They later return to the rooftop to prevent her from getting away, where Harley continues to pester her over her not having a sense of humor. Shiva tells Harley a joke and knocks Cheshire unconscious as she sneaks up behind Harley. Harley later tells her that she has "the makings of a great comedienne".
In Cold Blooded, she watches Ivy's dancing flowers show forces and asks a sneezing Frost if she is ill. She and other students later confronts Firefly as he carries a hostage through the sky, and tells Frost to go to bed after her freezing sneeze hits not only Firefly, but also Principal Waller's helicopter and the other students.
In the film Hero of the Year, Lady Shiva appears as a nominee for Hero of the Year and is suspicious of Big Barda's when she suddenly enrols at Super Hero High, continually trying to convince Waller that Barda is still evil, at one point bringing her to Waller accusing her of trying to sneak out of the school. After Barda saves her during the final battle against Eclipso's shadows, they befriend each other.
In Hero of the Month: Lady Shiva, Shiva is awarded Hero of the Month, and gets testimonials from Batgirl the Flash and Big Barda, the latter of whom she has a "girl's night out" with, defeating a gang of men in a nighttime alley in her Hero of the Month VT.
In Body Electric, Lady Shiva makes a background appearance attending Thunder and Lightning's medal ceremony in the school auditorium for restoring power to Metropolis during a blackout. In Fresh Ares Part 2, she piles into the Battywagon with the other non-flying students to battle a rampaging Ares. After he is defeated, she appears with the other students celebrating in front of him. In Fresh Ares Part 3, he breaks free and the battle resumes. Frost creates an ice shield around her and other students but they are blown away by a fire blast from Ares. After his rampage ends when he is given back the Amulet of Harmonia, Shiva appears watching him with the other students.
In Fight Flub, she attends an advanced martial arts class where she shows off her skills on a target. She and most of the rest of the class are then moved to the sparring mats by Coach Wildcat. In A New Perry-Spective, she works on the shields to the Battywagon for her shop midterm with Batgirl and Big Barda, before taking it for a test drive to pursue a known criminal spotted in Metropolis. They encounter Granny Goodness' old pet, Perry rampaging through the city, and Shiva saves a civilian from Perry's path using a telescopic hand in the Battywagon before capturing him in a net. After Barda convinces Batgirl and Shiva that he is harmless and not part of a plot by Granny Goodness, she adopts him and reminds Shiva that "we all deserve a second chance". In It's a Superful Life, Shiva makes a background appearance attending the SHHS Winter Holiday tree ceremony in the school foyer, where she enjoys the snowfall created by Frost.
In Fish Out of Water Part 2, Lady Shiva makes a cameo appearance standing in front of the school with the Flash and Star Sapphire at night. In By the Yearbook, she makes a background appearance looking through a completed SHHS yearbook with Mammoth in the school hallway.
In the first part of Fortress of Solidarity, Lady Shiva makes a cameo appearance attending the SHHS winter holiday tree ceremony, wearing skates and watching as Trigon enters the school by burning a hole through the skating rink around the tree.
- "Welcome to Super Hero High"
- "All About Super Hero High"
- "Fall Into Super Hero High"
- "Hero of the Month: Bumblebee"
- "Batgirl vs. Supergirl"
- "Hero of the Month: Harley Quinn"
- "Hero of the Month: Hawkgirl"
- "The Cheetah Who Cried Wolf"
- "Roomies Return: Frost's Bite"
- "The Odd Couple"
- "Cold Blooded"
- "Hero of the Year"
- "Hero of the Month: Lady Shiva"